The páramo is a neotropical alpine ecosystem that covers more than 75,000 km2 of the northern Andes of Colombia, Ecuador, Venezuela, and Peru. It provides important environmental services: more than 10 million people in the Andean highlands benefit from the water supply and regulation function, which is attributed to the volcanic soils that underlie the ecosystem. The soils are also major carbon sinks of global significance. Severe land use changes and soil degradation threaten both the hydrology and carbon sink function. Nevertheless, soil genesis and properties in the páramo is rather poorly understood, nor are their ecological functions well documented. The impact of the geomorphology of the páramo on soil genesis was studied in the rio Paute basin, south Ecuador. Two toposequences were described and analysed. In each toposequence, four pedons were selected representing summit, backslope, undrained plain situation, and valley bottom positions in the landscape. The soils are classified as Hydric Andosols in the World Reference Base for Soil Resources and Epiaquands or Hydrudands in Soil Taxonomy. They are very acidic and have a high organic matter content, high P deficiency, and Al toxicity. Their water content ranges from 2.64 g g-1 at saturation, down to 1.24 g g-1 at wilting point, resulting in a large water storage capacity. Two major soil forming processes are identified: (1) volcanic ash deposition and (2) accumulation of organic carbon. Volcanic ash deposits may vary in depth as a result of regional geomorphological factors such as parent material, orientation, slope, and altitude. Organic carbon accumulation is an interaction of both waterlogging, which depends on the position in the landscape, and the formation of organometallic complexes with Al and Fe released during volcanic ash breakdown. Despite the high variability in parent material and topography, the soil is characterised by a notable homogeneity in physico-chemical properties. Statistical analysis reveals that only topographic location has a slight but significant influence on soil pH as well as the organic matter content, saturated conductivity and water retention at high pressure. Finally, the exceptional properties of these soils provide useful insights to improve classification of the Andosols reference group of the FAO World reference Base for Soil Resources. © 2005 Elsevier B.V. All rights reserved.