Title
New approach to sulfonated diphosphine complexes: Synthesis and amphoteric behaviour of zwitterionic [Mn+(CO4{(PPh2) 2C(H)SO3-}]
Date Issued
14 October 2005
Access level
metadata only access
Resource Type
journal article
Author(s)
Universidad de Oviedo
Publisher(s)
Royal Society of Chemistry
Abstract
Oxidation of the thioketone residue in the complex [Mn(CO) 4{(PPh2)2C=S}]+ (2) with hydrogen peroxide affords the sulfonate derivative [Mn(CO)4{(PPh 2)2C(H)SO3}] (3), which shows amphoteric behaviour in reversible acid-base processes, and is easily chlorinated to give [Mn(CO)4{(PPh2)2C(Cl)SO3}] (8). © The Royal Society of Chemistry 2005.
Start page
4860
End page
4862
Issue
38
Language
English
OCDE Knowledge area
Química inorgánica, Química nuclear
Química orgánica
DOI
Scopus EID
2-s2.0-27144439516
Source
Chemical Communications
ISSN of the container
13597345
Sources of information:
Directorio de Producción Científica
Scopus