In this paper, we consider the quantization of the 2D BF model coupled to topological matter. Guided by the rigid supersymmetry, this system can be viewed as a super-BF model, where the field content is expressed in terms of superfields. A canonical analysis is done and the constraints are then implemented at the quantum level in order to construct the Hilbert space of the theory under the perspective of loop quantum gravity methods. © 2012 IOP Publishing Ltd.