Title
Solvent randomness and intramolecular considerations of optical responses in four-wave mixing
Date Issued
01 January 2021
Access level
metadata only access
Resource Type
journal article
Author(s)
Espinoza-Montero P.
González-Paz L.A.
Vera-Villalobos J.
Mora J.R.
Alvarado Y.J.
Universidad del Norte
Publisher(s)
Taylor and Francis Ltd.
Abstract
We determined the optical profiles of a molecular system coupled with a thermal bath in presence of intramolecular coupling. Solvent effects were explicitly considered as a random variable by modelling the non-radiative interaction with the solute. Optical susceptibilities of stochastic origin were solved through cumulant expansions in Gaussian distributions considering a white noise as a correlation function. We examined the behaviour of these properties for the solvent noise parameter and intramolecular coupling parameters. Our results show that the intensity of the nonlinear optical properties decreases with the insertion of either of the two effects considered. Finally, other considerations related to the determination of relaxation times from the symmetry properties of the optical responses in frequency space are presented.
Start page
1083
End page
1093
Volume
68
Issue
20
Language
English
OCDE Knowledge area
Óptica
Subjects
Scopus EID
2-s2.0-85115148483
Source
Journal of Modern Optics
ISSN of the container
09500340
Sources of information:
Directorio de Producción Científica
Scopus