Title
Recent Developments in Chain-Growth Polymerizations of Conjugated Polymers
Date Issued
19 July 2017
Access level
metadata only access
Resource Type
review
Author(s)
Aplan M.P.
Pennsylvania State University
Publisher(s)
American Chemical Society
Abstract
In this Review, we discuss recent developments and advancements in chain-growth polymerizations for conjugated polymers. Controlled synthesis methods will produce conjugated polymers with finely tuned properties and facilitate their development in new industrial applications. We begin with a discussion on the inherent differences between step-growth, chain-growth, and controlled chain-growth polymerization mechanisms. We emphasize that verification of polymerization mechanisms by kinetic analyses is necessary for the development of new controlled polymerizations. Next, we highlight recent advances in this rapidly growing field. Controlled syntheses of conjugated polymers usually employ a catalyst transfer mechanism, but techniques utilizing different controlled mechanisms are also beginning to emerge. We then highlight reported limitations that serve as a platform for future studies. Finally, to emphasize the potential of controlled chain-growth polymerizations, the synthesis of conjugated block copolymers by sequential chain-growth reactions is briefly discussed.
Start page
7888
End page
7901
Volume
56
Issue
28
Language
English
OCDE Knowledge area
Ingeniería química
Ciencia de los polímeros
Scopus EID
2-s2.0-85025597072
Source
Industrial and Engineering Chemistry Research
ISSN of the container
08885885
Sponsor(s)
Financial support from the Office of Naval Research under Grant N000141410532 is gratefully acknowledged.
Sources of information:
Directorio de Producción Científica
Scopus