Title
Harmonic force constants of boron trihalides and some mixed halides of boron
Date Issued
20 February 1994
Access level
metadata only access
Resource Type
journal article
Author(s)
Anacona J.
Universidad de Oriente
Abstract
A reliable set of harmonic force constants was calculated for BF3, BCl3, BBr3, BI3, BF2Cl, BF2Br, BCl2F, BCl2Br, BBr2F, and BBr2Cl using the observed vibrational frequencies of these compounds (containing 10B or 11B isotopes) and the iterative consistency method. The final force field reproduces quite satisfactorily the experimental frequencies. Some of the principal stretching force constants were found to vary systematically with the electronegativity of the halogen. © 1994.
Start page
279
End page
284
Volume
304
Issue
3
Language
English
OCDE Knowledge area
Química orgánica
Scopus EID
2-s2.0-0542358934
Source
Journal of Molecular Structure: THEOCHEM
ISSN of the container
01661280
Sponsor(s)
We wish to thank the Research Committee of the Universidad de Oriente for financial assistance covering part of this work.
Sources of information:
Directorio de Producción Científica
Scopus