Title
Comparison of static and light-induced thermal hystereses of a spin-crossover solid, in a mean-field approach
Date Issued
19 March 2001
Access level
metadata only access
Resource Type
journal article
Author(s)
Enachescu C.
Varret F.
Universitȩ de Versailles/St
Publisher(s)
Institute of Physics Publishing
Abstract
We investigate the relationship between the two mean-field models which have been proposed independently for characterizing the static and the light-induced thermal hystereses of spin-transition solids, respectively involving an interaction parameter J and a relaxation self-acceleration parameter α. We unify these two models into a unique - static and dynamic - mean-field description based on Arrhenius thermal activation processes. The model is used to analyse the experimental hysteresis loops, the relaxation curves in the dark, and the light-induced instability in the spin-crossover system [FexCo1-x(btr)2(NCS)2] H2O. A linear relationship between J and αT is obtained, which is in qualitative agreement with the available theories.
Start page
2481
End page
2495
Volume
13
Issue
11
Language
English
OCDE Knowledge area
Ingeniería de materiales Física de la materia condensada
Scopus EID
2-s2.0-0035911522
Source
Journal of Physics Condensed Matter
ISSN of the container
09538984
Sources of information: Directorio de Producción Científica Scopus