Title
One-dimensional Ising-like systems: An analytical investigation of the static and dynamic properties, applied to spin-crossover relaxation
Date Issued
02 May 2000
Access level
metadata only access
Resource Type
research article
Author(s)
Groupe d'Etude de la Matière Condensée, CNRS-Université de Versailles
Abstract
We investigate the dynamical properties of the 1-D Ising-like Hamiltonian taking into account short and long range interactions, in order to predict the static and dynamic behavior of spin crossover systems. The stochastic treatment is carried out within the frame of the local equilibrium method [1]. The calculations yield, at thermodynamic equilibrium, the exact analytic expression previously obtained by the transfer matrix technique [2]. We mainly discuss the shape of the relaxation curves: (i) for large (positive) values of the short range interaction parameter, a saturation of the relaxation curves is observed, reminiscent of the behavior of the width of the static hysteresis loop [3]; (ii) a sigrnoidal (self-accelerated) behavior is obtained for large enough interactions of any type; (iii) the relaxation curves exhibit a sizeable tail (with respect to the mean-field curves) which is clearly associated with the transient onset of first-neighbor correlations in the system, due to the effect of short-range interactions. The case of negative short-range interaction is briefly discussed in terms of two-step properties.
Start page
317
End page
326
Volume
15
Issue
2
Language
English
OCDE Knowledge area
Física de partículas, Campos de la Física
Subjects
Scopus EID
2-s2.0-0001558606
Source
European Physical Journal B
ISSN of the container
14346028
Sources of information:
Directorio de Producción Científica
Scopus