Title
Electrochemical sensing using magnetic molecularly imprinted polymer particles previously captured by a magneto-sensor
Date Issued
01 May 2018
Access level
open access
Resource Type
journal article
Publisher(s)
Elsevier B.V.
Abstract
The determination of 1-chloro-2,4-dinitrobenzene (CDNB) was used as a proof-of-concept to a simple analytical practical configuration applying magnetic molecularly imprinted particles (mag-MIPs). Mag-MIPs were captured from an emulsion by a home-made magneto-sensor (where a small magnet was entrapped by a graphite-epoxy composite) and then, this sensor, was transferred to the solution containing the analyte, where, after binding to the mag-MIPs, the analyte was directly analysed using differential pulse voltammetry (DPV) since the magneto-sensor acted as the working electrode. After optimization, a detection limit of 6.0 μmol L−1 with a RSD of 2.7% was achieved along with suitable recoveries and selectivity. This methodology offers a different approach for electroanalytical methodologies using mag-MIPs.
Start page
19
End page
23
Volume
181
Language
English
OCDE Knowledge area
Ciencia de los polímeros Electroquímica
Scopus EID
2-s2.0-85039955235
PubMed ID
Source
Talanta
ISSN of the container
00399140
Source funding
INNOVATE PERU
Sponsor(s)
The authors would like to express their sincerest gratitude and indebtedness to the Research Funding Agencies Programa Nacional de Innovación para Competitividad y Productividad - InnovatePeru (Convenio 513-INNOVATEPERU-ECIP-2015), CNPq (303690/2012-7 and 465571/2014-0), FAPESP (2014/25264-3, 2014/50945-4 and 2016/06926-0) for the financial support. GP wishes to acknowledge IGI-Institute of Research of National University of Engineering of Lima – Peru (project FC-F-24–2017). The Spanish Ministry of Economy and Competitiveness (MINECO), Madrid (project BIO2016-75751-R) is also acknowledged. SK wishes to acknowledge PRODOC-CAPES. LMG (SFRH/BPD/76544/2011 and FCT/13277/4/8/2015S) wishes to acknowledge Fundação para a Ciência e a Tecnologia (FCT).
Sources of information: Directorio de Producción Científica Scopus