Title
On the Origin of the Ideality Factor in Perovskite Solar Cells
Date Issued
01 July 2020
Access level
open access
Resource Type
journal article
Author(s)
Caprioglio P.
Wolff C.M.
Sandberg O.J.
Armin A.
Albrecht S.
Neher D.
Stolterfoht M.
Institute for Silicon Photovoltaics
Publisher(s)
Wiley-VCH Verlag
Abstract
The measurement of the ideality factor (nid) is a popular tool to infer the dominant recombination type in perovskite solar cells (PSC). However, the true meaning of its values is often misinterpreted in complex multilayered devices such as PSC. In this work, the effects of bulk and interface recombination on the nid are investigated experimentally and theoretically. By coupling intensity-dependent quasi-Fermi level splitting measurements with drift diffusion simulations of complete devices and partial cell stacks, it is shown that interfacial recombination leads to a lower nid compared to Shockley–Read–Hall (SRH) recombination in the bulk. As such, the strongest recombination channel determines the nid of the complete cell. An analytical approach is used to rationalize that nid values between 1 and 2 can originate exclusively from a single recombination process. By expanding the study over a wide range of the interfacial energy offsets and interfacial recombination velocities, it is shown that an ideality factor of nearly 1 is usually indicative of strong first-order non-radiative interface recombination and that it correlates with a lower device performance. It is only when interface recombination is largely suppressed and bulk SRH recombination dominates that a small nid is again desirable.
Volume
10
Issue
27
Number
2000502
Language
English
OCDE Knowledge area
Ingeniería de materiales
Scopus EID
2-s2.0-85085943003
Source
Advanced Energy Materials
ISSN of the container
16146832
Sponsor(s)
Funding text 1 M.S. acknowledges the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)—Project No. 423749265—SPP 2196 (SURPRISE) for funding. S.A. acknowledges funding from the German Federal Ministry of Education and Research (BMBF), within the project “Materialforschung für die Energiewende” (Grant No. 03SF0540), and the German Federal Ministry for Economic Affairs and Energy (BMWi) through the “PersiST” project (Grant No. 0324037C). Additional funding came from HyPerCells (a Joint Graduate School of the Potsdam University and the Helmholtz‐Zentrum Berlin) and by the DFG (German Research Foundation)—Project‐ID 182087777—SFB 951. A.A. was supported by Sêr Cymru Program through the European Regional Development Fund, and Welsh European Funding Office. Funding text 2 M.S. acknowledges the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)—Project No. 423749265—SPP 2196 (SURPRISE) for funding. S.A. acknowledges funding from the German Federal Ministry of Education and Research (BMBF), within the project “Materialforschung für die Energiewende” (Grant No. 03SF0540), and the German Federal Ministry for Economic Affairs and Energy (BMWi) through the “PersiST” project (Grant No. 0324037C). Additional funding came from HyPerCells (a Joint Graduate School of the Potsdam University and the Helmholtz-Zentrum Berlin) and by the DFG (German Research Foundation)—Project-ID 182087777—SFB 951. A.A. was supported by Sêr Cymru Program through the European Regional Development Fund, and Welsh European Funding Office. Helmholtz-Zentrum für Umweltforschung - UFZ
Sources of information: Directorio de Producción Científica Scopus