Objective The aim was the preliminary psychometric analysis of the Brief Scale of Study Satisfaction (BSSS) in college students. Method The sample consisted of 590 students (75.9% women) between 17 and 47 years old (Mean = 20.37; SD = 3.155). Depression and anxiety measures (GAD-2 and PHQ-2) were also used. An exploratory factor analysis to jointly differentiate the EBSE, GAD-2, and PHQ-2 was applied to data. Finally, the score reliability was assessed by the coefficient alpha. Results A two-factor structure was found, one of Satisfaction with Studies (42% variance), and another of Affection Negative (Anxiety and Depression, 22% variance), thus providing evidence of construct validity of the EBSE. In addition, the reliability was adequate (.788). Conclusion The EBSE is a suitable measurement tool with initially good psychometric properties. The practical implications and limitations of the study are discussed.