Title
Graphene modulated LiMn<inf>1.5</inf>Ni<inf>0.4</inf>Cr<inf>0.1</inf>O<inf>4</inf>spinel cathode for lithium ion battery
Date Issued
01 September 2020
Access level
open access
Resource Type
journal article
Author(s)
Katiyar R.K.
Tripathi B.
Tiwari A.
Adireddy S.
Dixit A.
Weiner B.R.
Morell G.
Katiyar R.S.
University of Puerto Rico
Publisher(s)
Institute of Physics
Abstract
We report the development of a rechargeable lithium ion battery with homogeneous mixing of 10% of graphene oxide in active LiMn1.5Ni0.4Cr0.1O4 cathode material for enhanced electrochemical performance. The redox behavior of the cell, which is normally too slow for practical applications, is accelerated with highly conductive graphene. Intimate mixing of the two materials is achieved by a slurry maker using an organic solution for a cathode paste. The fabricated electrode is repeatedly charged/discharge at C/10 and C/2 rates without any significant degradation in the electrochemical capacity. The gravimetric energy density of the composite cathode material exceeds that of the LiMn1.5Ni0.4Cr0.1O4 oxide electrode in lithium-ion batteries, and the addition of graphene in active material is likely to prove advantageous in applications where weight, rather than volume, is a critical factor.
Volume
1
Issue
2
Language
English
OCDE Knowledge area
Física y Astronomía
Subjects
Scopus EID
2-s2.0-85129233695
Source
Nano Express
Sponsor(s)
Funding text
This work was supported by the grant from NSF-CAWT project OIA-1849243. NASA MIRO SPRInT Grant No. 80NSSC19M0236, and NASA EPSCoRGrant No. 80NSSC19M0049.
Sources of information:
Directorio de Producción Científica
Scopus