Title
Self assembly of silver(i) coordination polymers formed through hydrogen bonding with a new ditopic heteroscorpionate ligand
Date Issued
20 August 2009
Access level
metadata only access
Resource Type
research article
Author(s)
San Diego State University
Abstract
The new ditopic heteroscorpionate ligand, (3-methoxy-4-hydroxyphenyl)bis(3, 5-dimethylpyrazolyl)methane (L5v), and four coordination polymers of silver Ag(i) derived therefrom, have been synthesized and characterized by X-ray diffraction, ESI-MS, IR spectroscopy and elemental analysis. The presence of different anions (i.e. BF4-, CF3SO 3-, NO3-, or SbF6-) lead to different crystal packing schemes due to different H-bonding patterns that depend on the relative charge delocalization and/or shape of the anion. © The Royal Society of Chemistry 2009.
Start page
6599
End page
6605
Issue
33
Language
English
OCDE Knowledge area
Química orgánica
Scopus EID
2-s2.0-68749105882
Source
Dalton Transactions
ISSN of the container
14779226
Sources of information: Directorio de Producción Científica Scopus