Title
Synthesis and structures of aryloxo- and binaphthoxogermanium(IV) alkyl iodide complexes
Date Issued
15 December 2010
Access level
metadata only access
Resource Type
conference paper
Author(s)
Wetherby A.E.
Schrick A.C.
Dipasquale A.
Golen J.A.
Rheingold A.L.
Weinert C.S.
Oklahoma State University
Publisher(s)
Elsevier S.A.
Abstract
The germanium(II) aryloxide complexes (S)-[Ge{O2C 20H10-(SiMe2Ph)2-3,3′}{NH 3}] (1) and [Ge(OC6H3Ph2-2,6) 2] (2) react with either ButI or MeI to yield the corresponding germanium(IV) compounds (S)-[Ge{O2C20H 10-(SiMe2Ph)2-3,3′}{But}{I}] (3), (S)-[Ge{O2C20H10-(SiMe2Ph) 2-3,3′}{Me}{I}] (4), [Ge(OC6H3Ph 2-2,6)2(But)(I)] (5), and [Ge(OC 6H3Ph2-2,6)2(Me)(I)] (6). Compound 6 reacts with 2,6-diphenylphenol to yield [Ge(OC6H3Ph 2-2,6)3(Me)] (7), while 3-5 do not. The X-ray crystal structures of 3-5 and 7 were determined, and 3-5 represent the first structurally characterized germanium(IV) species having germanium bound to both oxygen and iodine. © 2010 Elsevier B.V. All rights reserved.
Start page
89
End page
95
Volume
364
Issue
1
Language
English
OCDE Knowledge area
Química orgánica
Métodos de investigación bioquímica
Subjects
Scopus EID
2-s2.0-78649722005
Source
Inorganica Chimica Acta
ISSN of the container
00201693
Conference
Inorganica Chimica Acta
Sources of information:
Directorio de Producción Científica
Scopus