Title
Scientific insights of electrochemical replacement approach to describe the origin of Pre-Columbian Peruvian gilded copper-based objects
Date Issued
23 November 2021
Access level
open access
Resource Type
conference paper
Author(s)
Alviz-Meza A.
Chipoco Haro D.A.
Velarde M.I.
Publisher(s)
IOP Publishing Ltd
Abstract
Pre-Columbian Peruvian goldsmiths developed gilded copper-based objects by ancient techniques that require identification to propose conservation strategies. Lechtman H, conducted experiments to suggest that the electrochemical replacement was the gilding technique used by the Moche and Vicus cultural groups. Despite her remarkable achievement, the quantitative data provided by her is still open to discussion. This work focused on obtaining experimental data to recreate her protocol by introducing less gold precursor. Polished copper pieces were plated with an adherent gold film of up to 7.5 µm after immersing them into an electrolytic solution for 3 min and 6 min at 80 ºC. Our results demonstrated that the electrochemical replacement technique gives rise to anodic regions in the plated objects. Further studies around the corrosion process that undergoes these heritage objects in burial and environmental conditions are suggested to determine their deterioration rate. Moreover, electroless and galvanic techniques should be explored in order to improve current approaches.
Volume
2118
Issue
1
Language
English
OCDE Knowledge area
Ingeniería química
Scopus EID
2-s2.0-85121606074
Source
Journal of Physics: Conference Series
ISSN of the container
17426588
Conference
1st International Conference on Physical Problems of Engineering, ICPPE 2021
Sponsor(s)
The authors acknowledge to Concytec/Banco Mundial for their financial support in the Project "Mejoramiento y Ampliación de los Servicios del Sistema Nacional de Ciencia Tecnología e Innovación Tecnológica, 8682-PE” through its executing unit FONDECYT, contract number 035-2019. This project could not have been possible without the valuable collaboration of Juan Carlos Rodríguez Reyes, Ismat Shah, Carsten Benndorf, and Andrés De Leo, Centro de Investigación para la Conservación del Patrimonio, Universidad de Ingeniería y Tecnología (UTEC), Perú, whom we thank for their scientific advice. Also, Andrea Arana, Mario Carbajal, and Karinna Visurraga are thanked for their management support at UTEC.
Sources of information: Directorio de Producción Científica Scopus