Title
Elastic origin of the unsymmetrical thermal hysteresis in spin crossover materials: Evidence of symmetry breaking
Date Issued
01 January 2021
Access level
open access
Resource Type
research article
Author(s)
Université Paris-Saclay
Abstract
The jungle of experimental behaviors of spin-crossover materials contains a tremendous number of unexpected behaviors, among which, the unsymmetrical hysteresis loops having different shapes on heating and cooling, that we often encounter in literature. Excluding an extra effect of crystallographic phase transitions, we study here these phenomena from the point of view of elastic modeling and we demonstrate that a simple model accounting for the bond lengths misfits between the high-spin and low-spin states is sufficient to describe the situation of unsymmetrical hysteresis showing plateaus at the transition only on cooling or on heating branches. The idea behind this effect relates to the existence of a discriminant elastic frustration in the lattice, which expresses only along the high-spin to low-spin transition or in the opposite side. The obtained two-step transitions showed characteristics of self-organization of the spin states under the form of stripes, which we explain as an emergence process of antagonist directional elastic interactions inside the lattice. The analysis of the spin state transformation inside the plateau on cooling in terms of two sublattices demonstrated that the elastic-driven self-organization of the spin states is accompanied with a symmetry breaking.
Volume
13
Issue
5
Language
English
OCDE Knowledge area
Física atómica, molecular y química
Subjects
Scopus EID
2-s2.0-85106666356
Source
Symmetry
Sponsor(s)
This research was funded by ANR (Agence Nationale de la Recherche Scientifique), grant number Mol-CoSM N◦ ANR-20-CE07-0028-02 and the Universities of Versailles and Paris-SaclayUPSAY, and the CNRS (Centre National de la Recherche Scientifique) and Ambassade de France au Sénégal. We thank all of them for their financial support.
Funding: This research was funded by ANR (Agence Nationale de la Recherche Scientifique), grant number Mol-CoSM N◦ ANR-20-CE07-0028-02 and the Universities of Versailles and Paris-Saclay-UPSAY, and the CNRS (Centre National de la Recherche Scientifique) and Ambassade de France au Sénégal. We thank all of them for their financial support.
Sources of information:
Directorio de Producción Científica
Scopus