Title
Analysis of hysteretic spin transition and size effect in 3D spin crossover compounds investigated by Monte Carlo Entropic sampling technique in the framework of the Ising-type model
Date Issued
25 February 2015
Access level
open access
Resource Type
conference proceedings
Author(s)
Chiruta D.
Dahoo P.R.
Dimian M.
Université de Versailles Saint-Quentin-en-Yvelines
Publisher(s)
Institute of Physics Publishing
Abstract
In spin crossover (SCO) systems, the shape of the hysteresis curves are closely related to the interactions between the molecules, which these play an important role in the response of the system to an external parameter. The effects of short-range interactions on the different shape of the spin transition phenomena were investigated. In this contribution we solve the corresponding Hamiltonian for a three-dimensional SCO system taking into account short-range and long-range interaction using a biased Monte Carlo entropic sampling technique and a semi-analytical method. We discuss the competition between the two interactions which governs the low spin (LS) - high spin (HS) process for a three-dimensional network and the cooperative effects. We demonstrate a strong correlation between the shape of the transition and the strength of short-range interaction between molecules and we identified the role of the size for SCO systems.
Volume
585
Issue
1
Language
English
OCDE Knowledge area
Ingeniería eléctrica, Ingeniería electrónica
Scopus EID
2-s2.0-84957824477
Source
Journal of Physics: Conference Series
ISSN of the container
17426588
Sponsor(s)
European Social Fund through Sectoral Operational Program Human Resources 2007-2013 (PRO-DOCT)Stefan cel Mare University, Suceava
Sources of information: Directorio de Producción Científica Scopus