Title
The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
Date Issued
2013
Access level
restricted access
Resource Type
journal article
Author(s)
Rodriguez, J
Onna, D
Marchi, MC
Candal, R
Ponce, S
Bilmes, SA
Publisher(s)
Elsevier B.V.
Abstract
Spray pyrolysis (SP) and spray-gel (SG) techniques were used to deposit ZnO seeds on Fluor doped tin oxide glasses (FTO), heated at 350 C or 130 C, and PET heated at 90 C. The effect of seeding on the morphology and wettability of ZnO nanorods (NRs) films grown by wet chemical methods was analyzed. The morphology and wettability of ZnO NRs films depend on the seeding process. SP seeds formed from zinc acetate dissolved in water ethanol mixtures yield vertically aligned ZnO NRs, whose diameters and dispersion size are determined by the ethanol/water ratio in the precursor solution. SG seeds formed from a methanol ZnO sol produce a ring patterned distribution on the FTO substrate. The drying of ZnO sol drops impinging on the substrate produces high density of seeds along a ring yielding textured films with NRs vertically oriented on the rings and multi-oriented outside them. This effect was not observed when ZnO NRs grown onto the ZnO/PET substrate, however rod diameter is related with the density of seeds. This way to control the density and diameter of NRs deposited onto a substrate modify the wettability and opens new possibilities for the design of tailored nanomaterials for photochemical applications. Both type of NRs films showed a strong luminescence emission in the UV and in the blue, associated with surface and intrinsic defects. © 2013 Published by Elsevier B.V.
Start page
197
End page
203
Volume
279
Number
9
Language
English
Scopus EID
2-s2.0-84878593454
Source
Applied Surface Science
ISSN of the container
0169-4332
Sponsor(s)
This work was supported by the Peruvian-Argentinean 321-2009-CONCYTEC OAJ Project and MINCYT-CONCYTEC PE/09/01 and PE/11/02, CONICET-PIP 112-200801-02533, UBACyT X003 and 20020090100297. RJC and SAB are members of CONICET. DO UBA fellowship is acknowledged. We are grateful to Dr. F. Chandezon for fruitful discussions. One of the authors, J. Rodriguez, wishes to thank to the “Convenio de Desempeño, UTA-Mineduc” for financial support.
Sources of information: Directorio de Producción Científica