Title
Low temperature neutron diffraction study of MgCr<inf>2</inf>O<inf>4</inf> spinel
Date Issued
12 March 2008
Access level
metadata only access
Resource Type
research article
Author(s)
Williams A.J.
Gordon C.D.
Klemme S.
Attfield J.P.
University of Edinburgh
Abstract
The low temperature structural and magnetic transition in the normal spinel MgCr2O4 has been studied using high resolution neutron powder diffraction. The transition from a cubic, paramagnetic phase (space group , a = 8.3329(1) at 19K) to a tetragonal, antiferromagnetically ordered structure (I41/amd, a = 5.8961(1) and c = 8.3211(1) at 10K) occurs via a sharp first order transition at 12.4K. A small hysteresis of 0.15K between cooling and warming experiments is observed. The structural and magnetic transitions are coincident and their order parameters (the tetragonal strain and Cr moment) scale with each other. The structural transition partially relieves magnetic frustration in the Cr network, although remaining frustration is evident from the low value (1.63νB) of the saturated Cr 3+moment. © IOP Publishing Ltd.
Volume
20
Issue
10
Language
English
OCDE Knowledge area
Física de la materia condensada
Scopus EID
2-s2.0-41849126415
Source
Journal of Physics Condensed Matter
ISSN of the container
09538984
Sources of information: Directorio de Producción Científica Scopus