Title
Contribution of differential scattering of circularly polarized light to the optical rotatory dispersion of a sample
Date Issued
01 November 1984
Access level
metadata only access
Resource Type
journal article
Author(s)
University of New Mexico
Publisher(s)
Optica Publishing Group
Abstract
A chiral scattering molecule has the ability to interact differently with circularly polarized light of opposite polarization. This phenomenon has been termed circular intensity differential scattering. It is shown that the differential-scattering phenomenon contributes to the total optical rotatory dispersion (ORD) of the sample. This contribution is independent of the presence of chromophores in the sample. From two general relations, (1) the Kronig–Kramers transforms, obeyed by linear, causal systems, and (2) the optical theorem, a result of energy conservation and power flow, the contribution of the preferential scattering of circularly polarized light to the ORD of the sample is formally obtained. It is seen that this contribution takes place through the circular preferential removal of the coherent part of the wave, i.e., the extinction (by means of scattering) of the transmitted radiation. It is shown that the use of approximations in the description of the internal field in the scattering equations can equivocally predict the absence of a scattering-dependent ORD contribution. © 1984 Optical Society of America.
Start page
1114
End page
1119
Volume
1
Issue
11
Language
English
OCDE Knowledge area
Física y Astronomía
Medicina básica
Nano-tecnología
Scopus EID
2-s2.0-0021523443
PubMed ID
Source
Journal of the Optical Society of America A: Optics and Image Science, and Vision
ISSN of the container
1084-7529
Sponsor(s)
National Institute of General Medical Sciences R37GM032543 NIGMS
Sources of information:
Directorio de Producción Científica
Scopus