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Browsing Publications by Department "Anorganisch-chemisches Institut der Universität"
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Publication
Novel Reactions of Phosphorus Ylides with Carbonyl(cyclopentadienyl)metal Complexes: Preparative Access to μ‐Alkylidene Complexes and Unexpected Acylations
(
1981-01-01
)
KORSWAGEN EDERY, RICHARD PAUL
;
Alt R.
;
Speth D.
;
Ziegler M.L.
[η5‐CpFe(CO)2]2 undergoes a previously unknown type of reaction with phoshorus ylides Ph3PCHR (RH, Me, iPr) to give the cis‐ and trans‐alkyli‐ene complexes 1 and 2 and a small amount of the organometal‐substituted ylide 3, Surprisingly, analogous manganese complexes react with methylenephosphorane with ortho‐acylation of one of the P‐phenyl groups. (Figure Presented.) Copyright © 1981 by Verlag Chemie, GmbH, Germany
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